4.7 Article

Heterometallic cobalt(II)-titanium(IV) oxo cages; key building blocks for hybrid materials

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 26, Pages 4701-4703

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00016g

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Funding

  1. EPSRC
  2. Engineering and Physical Sciences Research Council [EP/F00253X/1] Funding Source: researchfish
  3. EPSRC [EP/F00253X/1] Funding Source: UKRI

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The two new heterometallic cobalt(II)/titanium oxo cages octanuclear [Ti(7)O(5)(OEt)(19)(CoCl)] (1) and pentanuclear [Ti(4)O(OEt)(15)(CoCl)] (2) have been obtained via condensation reactions of Ti(OEt)(4) in the presence of CoCl(2). This simple methodology gives access to key well-defined molecular building blocks for Co-doped hybrid materials.

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