Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 7, Pages 1032-1034Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b923546a
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- ENSCP
- CNRS
- French Ministry of Higher Education and Research
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Grafting of [Ln(BH4)(3)(THF)(3)] (Ln = La, Nd) onto silica affords materials containing well-identified bis(borohydride) surface species. The neodymium-decorated silica converts the beta-butyrolactone monomer into highly isotactic poly(beta-hydroxybutyrate). Under similar conditions, the molecular precursor gives rise to an atactic polymer.
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