Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 40, Pages 7510-7512Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01560a
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Funding
- National Institutes of Health [GM 79465]
- Amgen
- Astra Zeneca
- Novartis
- Packard Foundation
- Sloan Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM079465] Funding Source: NIH RePORTER
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Lanthanide-based luminescent probes TPR1 and TPR2 were developed for the detection of hydrogen peroxide (H2O2) in living systems. The chemoselective reaction of these boronate-protected probes with H2O2 resulted in an enhanced lanthanide sensitization and a 6-fold increase in luminescent intensity. TPR2 was utilized to measure the endogenous production of H2O2 in RAW 264.7 macrophages using time-gated luminescent spectroscopy.
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