Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 28, Pages 5151-5153Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01335h
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Funding
- EPSRC [EP/D04779X/1, EP/F029292/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/D04779X/1, EP/F029292/1] Funding Source: researchfish
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Reaction of the bulky 6-membered N-heterocyclic carbene 6-Mes with Ni(cod)(2) gives a C-H activated 6-Mes nickel(II) complex, but the novel three-coordinate Ni(I) species Ni(6-Mes)(PPh(3))Br if the reaction is performed in the presence of Ni(PPh(3))(2)Br(2). The Ni(I) complex is a precursor for the catalytic hydrodehalogenation of aryl halides.
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