4.7 Article

Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M-2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 27, Pages 4962-4964

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00091d

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Funding

  1. Research Council of Norway [182056/S10]
  2. Office of Energy Efficiency and Renewable Energy, US Department of Energy
  3. European Commission [CP-CSA_INFRA-2008-1.1.1, 226507-NMI3]

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Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

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