Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 36, Pages 6822-6824Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01635g
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Mitsubishi Tanabe Pharma Corporation
- JSPS
- Grants-in-Aid for Scientific Research [21750097] Funding Source: KAKEN
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A copper-catalyzed addition of arylboronates to isatins has been developed to give 3-aryl-3-hydroxy-2-oxindoles under mild conditions. The catalytic cycle of this process has been examined through a series of stoichiometric reactions and an effective asymmetric variant has also been described by the use of a chiral N-heterocyclic carbene ligand.
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