Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 2, Pages 225-227Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920605a
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Funding
- NSF [CHE-0748525]
- Chemistry & Mol. Biology, NDSU
- Direct For Mathematical & Physical Scien [0748525] Funding Source: National Science Foundation
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Cucurbit[8]uril (as low as 10 mol%) acts as a supramolecular catalytic nanoreaction vessel and facilitates the photodimerization of coumarins in water leading to syn dimers. Saturation kinetics shows a sigmoidal dependence with a turnover number of 3.4 min(-1) and a Hill constant of 1.8 indicating a co-operative mechanism in the catalytic process.
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