Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 19, Pages 3360-3362Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b927336k
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CuSCN with enhanced p-type conductivity was prepared by replacing some of the cuprous sites by triethylamine coordinated Cu(I) with concomitant (SCN)(2) doping to introduce more holes. A compound Cu-5[(C2H5)(3)N](3)(SCN)(11) was isolated and well characterized. A 41% enhancement of energy conversion efficiency of the TiO2/N719/modified CuSCN cell from the best reported value and more than a factor of ten from bare CuSCN was achieved.
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