Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 5, Pages 788-790Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b920110f
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The structure-activity relations in the alumina-supported cobalt catalysts are studied at the realistic conditions of Fischer-Tropsch synthesis using in situ time-resolved XRD and catalytic measurements. Cobalt sintering during the first 3-5 h of the reaction and cobalt carbidisation at a longer time on stream (> 8 h) coincide with catalyst deactivation.
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