Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 32, Pages 5873-5875Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01753a
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- Deutsche Forschungsgemeinschaft
- Center of Materials Crystallography
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Reaction of LSi-SiL (1) (L = PhC(NtBu)(2)) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.
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