4.7 Article

Ordered mesoporous materials as solid supports for rhodium-diphosphine catalysts with remarkable hydroformylation activity

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 35, Pages 6587-6589

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00924e

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Funding

  1. Delft Research Centre for Sustainable Industrial Processes
  2. Dutch National Science Foundation NWO (NWO/STW)

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A rhodium-diphosphine complex based on Xantphos-type ligands was anchored on mesoporous silica SBA-15, and the material showed remarkably high catalytic activity in the hydroformylation of 1-octene, even exceeding its homogeneous analogue under certain conditions.

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