Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 7945-7947Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02904a
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- ARC
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Rapid CuAAC cross-coupling reactions catalyzed by CuBr/PMDETA in toluene afforded complex architectures from functional polymeric cyclic blocks. Various topologies (from paddle-like to 3-arm stars) rapidly formed with high conversion at 25 degrees C. Remarkably, this approach overcame significant steric hindrance linking polymeric cyclic structures with high coupling efficiency.
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