4.7 Article

Room-temperature spin crossover and Langmuir-Blodgett film formation of an iron(II) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 35, Pages 6464-6466

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01008a

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Funding

  1. University of Otago
  2. MacDiarmid Institute for Advanced Materials and Nanotechnology
  3. RSNZ Marsden Fund
  4. Swiss National Science Foundation

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[Fe-II(C(16)dpt)(2)(NCS)(2)]center dot 2/3H(2)O displays temperature-mediated spin crossover (SCO) with T-1/2 = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir-Blodgett film at an air-water interface.

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