4.7 Article

A novel gold-catalyzed chemoselective reduction of alpha,beta-unsaturated aldehydes using CO and H2O as the hydrogen source

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 9, Pages 1553-1555

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b922662a

Keywords

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Funding

  1. NSF of China [20633030, 20721063, 20873026]
  2. State Key Basic Research Program of PRC [2009CB623506]
  3. Science & Technology Commission of Shanghai Municipality [08DZ2270500]

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Chemoselective reduction of alpha,beta-unsaturated aldehydes in the presence of CO and H2O proceeds effectively over a ceria-supported gold catalyst system, providing a novel, efficient and clean approach to produce useful primary allyl alcohols with excellent activity and selectivity.

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