4.7 Article

TEMPO reacts with oxygen-centered radicals under acidic conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 28, Pages 5139-5141

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00547a

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In the presence of organic acids in organic media, 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) reacts with peroxyl radicals at nearly diffusion-controlled rates by proton-coupled electron transfer from the protonated nitroxide.

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