Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 7981-7983Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02589e
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- Swiss National Science Foundation (SNSF)
- University of Zurich
- US DOE
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Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H-2 interactions (7.8-6.8 kJ mol(-1)), which revealed the significant impact of internally polarized azulene backbone to stabilized H-2 molecules in the framework.
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