4.7 Article

[(FeLSCoLSIII)-Co-II](2) <-> [(FeLSCoHSII)-Co-III](2) photoinduced conversion in a cyanide-bridged heterobimetallic molecular square

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 47, Pages 8995-8997

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02024a

Keywords

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Funding

  1. Ministere de l'Enseignement Superieur et de la Recherche (MESR, France)
  2. Ministerio de Educacion y Ciencia (MEC, Spain) [CTQ2007-61690, CSD2007-00010]
  3. Generalitat Valenciana (GV, Spain) [PROMETEO/2009/108]
  4. Magmanet Network of Excellence [515767-2]

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The self-assembly of [Fe-III{B(pz)(4)}(CN)(3)](-) and [Co-II(bik)(2)(S)(2)](2+) affords the diamagnetic cyanide-bridged [(FeLSCoLSIII)-Co-II](2) molecular square which is converted into the corresponding magnetic [(FeLSCoHSII)-Co-III](2) species under light irradiation at relatively low temperatures.

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