Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 1, Pages 159-161Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b910298a
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- Ministry of Education, Culture, Sports, Science and Technology, Japan [17065001]
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Iridium complexes generated from [Ir(OMe)(COD)](2) and tris[3,5-bis(trifluoromethyl) phenyl] phosphine efficiently catalyzed the ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron in octane at 80 degrees C to produce the corresponding arylboronates in high yields with excellent regioselectivities.
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