Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 27, Pages 4974-4976Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00847h
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- Deutsche Forschungsgemeinschaft (DFG) within the frame of the competence network [546]
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For the first time, we demonstrated that combining oxidative and non-oxidative dehydrogenation of iso-butane in one reactor system is an attractive approach for iso-butene and hydrogen production. Iso-butene yields above 40% at iso-butene selectivity above 80% and COx selectivity below 2% were achieved over SiO2-supported highly-dispersed VOx species during at least 20 h on-stream at 833 K.
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