Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 3, Pages 466-468Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b918626c
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Funding
- Center of Novel Functional Molecule
- The Chinese University of Hong Kong
- Incentive Research Scheme [4440138]
- Hong Kong General Research Fund [2160344]
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Described are several classes of Ni(0) mediated cyanative alkene-aldehyde coupling reactions, providing 6-membered cores, which complement existing cyclization technology in several respects. Et2AlCN was used as both a cyclization accelerator and CN source. The NHC ligand may have a positive effect in differentiating reductive elimination and syn-beta-hydride elimination.
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