Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 8032-8034Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02357d
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The tandem hydroamination-annulation reaction of 4-pentyne-nitriles in the presence of amine nucleophiles and a cooperatively operating catalyst system, consisting of Ph(3)PAuCl and Zn(ClO(4))(2), provides an efficient route to 2-aminopyrroles. Two regioisomeric 2-aminopyrroles were formed in moderate to good yields.
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