Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 48, Pages 9250-9252Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc04043f
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Funding
- Academy of Finland [1118044, 217224]
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In this study, we developed an efficient and selective iron-based catalyst system for the synthesis of ketones from secondary alcohols and carboxylic acids from primary alcohol. In situ generated iron catalyst of thymine-1-acetate (THA) and FeCl3 under solvent-free condition exhibits high activity. As an example, 1-octanol and 2-octanol were oxidized to 1-octanoic acid and 2-octanone with 89% and 98% yields respectively.
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