4.7 Article

Shape controlled synthesis of palladium nanocrystals by combination of oleylamine and alkylammonium alkylcarbamate and their catalytic activity

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 45, Pages 8552-8554

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03485a

Keywords

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Funding

  1. Ministry of Science and Technology of China [2009CB930802]
  2. National Natural Science Foundation of China [20973177, 20932002]
  3. Chinese Academy of Sciences [KJCX2.YW.H16]

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The shape of Pd nanocrystals (NCs) can be controlled by combination of oleylamine (OAm) and alkylammonium alkylcarbamate (AAAC), and Pd spheres, tetrahedra and multipods have been synthesized. The multipods and tetrahedra are much more active than the spheres for hydrogenation reactions.

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