4.7 Article

Manganese(v)-oxo corroles in hydride-transfer reactions

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 43, Pages 8160-8162

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03373a

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Funding

  1. KRF/MEST of Korea
  2. GRL [2010-00353]
  3. WCU [R31-2008-000-10010-0]
  4. Ministry of Education, Culture, Sports, Science and Technology, Japan [20108010]

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Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(v)-oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (E(red)) of manganese(v)-oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

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