Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 47, Pages 9025-9027Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03347b
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- NSERC
- Canadian Foundation for Innovation
- Ontario Ministry of Research and Innovation
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The chelate effect of a tridentate receptor is exploited to determine halogen bonding association constants that vary by several orders of magnitude, including interactions of weak donors for which thermodynamic data were not previously available. Free energy relationships with computed and experimental properties hold over this wide range of donors. The strengths of iodine-and bromine-based halogen bonds, CH-anion and anion-arene interactions are compared.
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