4.7 Article

The first supraicosahedral bis(heteroborane)

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 39, Pages 7394-7396

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc02534h

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Funding

  1. EPSRC
  2. Engineering and Physical Sciences Research Council [EP/E02971X/1, GR/R99065/01] Funding Source: researchfish
  3. EPSRC [EP/E02971X/1] Funding Source: UKRI

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The first supraicosahedral bis(heteroborane), 1-(4'-Cp-4',1',6'-closo-CoC(2)B(10)H(11))-4-Cp-4,1,6-closo-CoC(2)B(10)H(11) has been synthesised as a mixture of racemic and meso diastereoisomers. Analysis of the molecular structures reveals clear evidence of internally crowded molecules.

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