4.7 Article

Encapsulation and selective recognition of sulfate anion in an azamacrocycle in water

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 33, Pages 6084-6086

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01699c

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Funding

  1. Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy via Oak Ridge National Laboratory
  2. National Center for Research Resources [G12RR013459]
  3. National Science Foundation [CHE-0821357]
  4. NATIONAL CENTER FOR RESEARCH RESOURCES [G12RR013459] Funding Source: NIH RePORTER

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Structural characterization of a sulfate complex with an azamacrocycle suggests that one sulfate is encapsulated in the macrocyclic cavity with eight hydrogen bonds; a significant selectivity of the host was observed for sulfate over halides, nitrate and perchlorate as evaluated by (1)H NMR studies in water.

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