4.7 Article

Enhancement of catalytic performance in asymmetric transfer hydrogenation by microenvironment engineering of the nanocage

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 43, Pages 8145-8147

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01401j

Keywords

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Funding

  1. National Basic Research Program of China [2009CB623503, 2010CB833300, 2008DFB50130]
  2. National Natural Science Foundation of China [20921092]

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Ru-TsDPEN confined in the nanocage with an amphiphilic microenvironment can be ten times more active than that with a hydrophobic one in the transfer hydrogenation of acetophenone in HCOONa-H2O, which is mainly due to the enhanced diffusion rates of reactants during the catalytic process.

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