4.7 Article

Transformation of a 1D to 3D coordination polymer mediated by low temperature lattice solvent loss

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 27, Pages 4899-4901

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00711k

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Funding

  1. Australian Research Council
  2. Australian Postgraduate Award scholarship

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The desolvation of lattice methanol from between the 1D chains in {[Cu(4,4'-bipyridine)(ccnm)(2)]center dot 4MeOH} (ccnm = carbamoylcyanonitrosomethanide) under ambient conditions, a weight loss of 22.4%, results in a solid state conversion to the 3D network [Cu(4,4'-bipyridine)(ccnm)(2)].

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