4.7 Article

Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)(2){BiCl2}]

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 42, Pages 7894-7896

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00639d

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The synthesis and full characterisation of trans-[PtCl(PCy3)(2){BiCl2}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy3)(2)]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.

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