4.7 Article

A bifunctionalized [3]rotaxane and its incorporation into a mechanically interlocked polymer

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 30, Pages 5536-5538

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00999g

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Funding

  1. National Natural Science Foundation of China [20625206, 20772126]
  2. National Basic Research Program [2007CB808004]
  3. Chinese Academy of Sciences

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A novel bifunctionalized [3]rotaxane based on a triptycene-derived macrotricyclic host was conveniently synthesized. On the basis of the [3]rotaxane, a linear main-chain poly[3]rotaxane was further obtained by the highly efficient Huisgen 1,3-dipolar cycloaddition.

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