4.7 Article

Self-assembly of looped triple-stranded helicates

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 7, Pages 1053-1055

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b921279e

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Funding

  1. Direccion General de Investigacion/FEDER [CTQ2007-60808/BQU]
  2. Fundacion Seneca [02992/PI/05]

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The reaction of the organogold metallaligand [(AuC Cbpyl)(2)(mu-Ph(2)P(CH(2))(4)PPh(2))] (bpyl = 2,2'-bipyridin-5-yl) with Fe(2+) or Zn(2+) ions gave helicates where the three ligand strands adopt a unique looped geometry.

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