4.7 Article

Platinum substituted boroles

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 6, Pages 916-918

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b923652j

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The unprecedented 1-metalloborole [(Cy3P)(2)Pt(Cl)(BC4Ph4)] (1) and its T-shaped cationic derivative (2) were successfully prepared and structurally characterized. Fine-tuning the electronics of the boron-bound metal complex leads to a significant change in the lowest electronic transition energy of the 1-metalloboroles.

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