4.7 Article

Isoprene polymerization with aminopyridinato ligand supported rare-earth metal complexes. Switching of the regio- and stereoselectivity

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 33, Pages 6150-6152

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00297f

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Funding

  1. National Natural Science Foundation of China [20934006]
  2. Ministry of Science and Technology of China [2005CB623802, 2009AA03Z501]

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The highly cis-1,4, trans-1,4 and 3,4-selective polymerizations of isoprene were successfully regulated by simply modifying the auxiliary ligands, metal centres and initiation groups of rare-earth metal complexes and cocatalysts.

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