Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 18, Pages 3083-3085Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c000263a
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [17350027, 18033041, 18065017, 19205009]
- JST, Japan
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This work reports the synthesis and characterization of the first water-soluble iridium porphyrin, iridium(III) diaqua porphyrin [Ir(III)(TSPP)(OH(2))(2)](3-) (1, TSPP = tetra-p-sulfonatophenyl porphyrin). The structure of 1 was unequivocally determined by single crystal X-ray analysis. Benzo-18-crown-6-ether is essential for producing single crystals suitable for X-ray analysis.
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