Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 15, Pages 2665-2667Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b925424b
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Funding
- National Natural Science Foundation of China [20972101]
- PCSIRTC [IRT0846]
- National Basic Research Program of China (973 Program) [2010CB833303]
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The asymmetric inverse-electron-demand aza-Diels-Alder reaction of N-Ts-1-aza-1,3-butadienes derived from 3-argiocarbonyl-coumarins and acetaldehyde has been developed using chiral secondary aminocatalysis, giving tricyclic chroman-2-one derivatives in high enantioselectivities (up to 95% ee).
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