4.7 Article

A facile one-step synthesis to cross-linked polymeric nanoparticles as highly active and selective catalysts for cycloaddition of CO2 to epoxides

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 19, Pages 3399-3401

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b926901k

Keywords

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Funding

  1. NSFC [20804031, 20964002]
  2. NSF of Gansu Province [0710RJZA110]
  3. NCET
  4. KPCMEC [207120]

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A very convenient one-step synthesis to cross-linked polymeric nanoparticles by conventional radical copolymerization without the addition of stabilizers or surfactants was explored. Moreover, these nanoparticles exhibited excellent stability, activity and selectivity in the cycloaddition reaction of CO2 to epoxides and could be separated from the products easily and reused.

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