Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 1, Pages 91-93Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b918616f
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Funding
- NIH [GM28962, DK31450]
- NATIONAL INSTITUTE OF DIABETES AND DIGESTIVE AND KIDNEY DISEASES [R01DK031450, R37DK031450] Funding Source: NIH RePORTER
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM028962, R37GM028962] Funding Source: NIH RePORTER
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[(ANS)Cu-I(CH3CN)](+) reacts with O-2 giving [{(ANS)Cu-II}(2)(mu-eta(2):eta(2)-O-2(2-))](2+), nu(O-O) = 731 cm(-1), shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O-2(2-) binding.
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