4.7 Article

Photo-induced water oxidation with tetra-nuclear ruthenium sensitizer and catalyst: A unique 4 x 4 ruthenium interplay triggering high efficiency with low-energy visible light

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 26, Pages 4725-4727

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00444h

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Funding

  1. CNR
  2. MIUR [20085ZXFEE, 20085M27SS]
  3. University of Messina
  4. University of Padova [2008, STPD08RCX]
  5. ESF [D35, D40]

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The combined use of a tetranuclear Ru(II) dendrimeric photosensitizer (1) and of a tretraruthenium substituted polyoxotungstate (2) as the catalyst enables photo-induced water oxidation at 550 nm producing O-2 with an outstanding quantum yield of 0.30.

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