4.7 Article

New insights into the acid mediated disproportionation of pentavalent uranyl

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 45, Pages 8648-8650

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03443f

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Funding

  1. Commissariat a l'Energie Atomique, Direction de l'Energie Nucleaire

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The reaction of benzoic acid with the uranyl(V) complex [(UO2Py5)(KI2Py2)] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

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