4.7 Article

Single chain magnet behaviour in an enantiopure chiral cobalt(II)-copper(II) one-dimensional compound

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 13, Pages 2322-2324

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b920231e

Keywords

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Funding

  1. Ministerio de Educacion y Ciencia (MEC, Spain) [CTQ2007-61690, CSD2007-00010, MAT2007-60660, CSD2006-00015]
  2. Generalitat Valenciana (GV, Spain) [PROMETEO/2009/108]
  3. Ministere de l'Enseignement Superieur et de la Recherche (MESR, France)
  4. Magmanet Network of Excellence [515767-2]

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The self-assembly of an enantiomerically pure, chiral dianionic oxamatocopper(II) complex with cobalt(II) ions leads to neutral oxamato-bridged heterobimetallic chains that combine chirality and slow magnetic relaxation, providing thus the first example of chiral single chain magnets (CSCMs).

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