4.7 Article

Spin crossover characteristics of nanofibrous Fe-II-1,2,4-triazole complexes in liquid crystals

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 8, Pages 1229-1231

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b920631k

Keywords

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Funding

  1. Japan Society for the Promotion of Science and by JST CREST [19205030]
  2. Japan Synchrotron Radiation Research Institute [2007A2048]
  3. Ministry of Education, Culture, Sports, Science and Technology
  4. Grants-in-Aid for Scientific Research [20111008] Funding Source: KAKEN

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A lipophilic linear Fe-II complex is dispersed as nanofibers in nematic liquid crystals and displays spin-crossover at temperatures higher than those observed for the bulk crystalline state; thermal bistability is also induced in the liquid crystal environment, reflecting increased ligand field splitting energy and enhanced cooperativity by liquid crystals.

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