Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 27, Pages 4985-4987Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00981d
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Funding
- Boston University
- Boston University and the Department of Chemistry
- NSF [CHE-0649114]
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Herein, we report an advancement in the application of visible light photoredox catalysts in a classic free radical mediated reaction, cyclization onto unactivated pi-systems. The reactive radical intermediate is generated by the single electron reduction of an activated C-Br bond by an electron-rich redox catalyst afforded by a visible light induced catalytic cycle.
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