4.7 Article

Living catalyzed-chain-growth polymerization and block copolymerization of isoprene by rare-earth metal allyl precursors bearing a constrained-geometry-conformation ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 17, Pages 3022-3024

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b926813h

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Funding

  1. The National Natural Science Foundation of China [20934006]
  2. The Ministry of Science and Technology of China [2005CB623802, 2009AA03Z501]

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Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.

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