Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 26, Pages 4806-4808Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc00094a
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Funding
- National Natural Science Foundation of China [20902018]
- Shanghai Pujiang Program [08PJ1403300]
- Fundamental Research Funds for the Central Universities
- 111 Project [B07023]
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Enantioselective organocatalytic phospha-Michael reaction of alpha,beta-unsaturated ketones and diaryl phosphine oxides has been developed for the first time employing multifunctional organocatalysts. Optically active products bearing quaternary chiral carbon stereocenters were obtained in high yields with good to excellent enantioselectivities (up to 98% ee).
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