4.7 Article

Strong donor-acceptor couplings in a special pair-antenna model

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 48, Pages 9176-9178

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc03665j

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Funding

  1. Centre National de la Recherche Scientifique (CNRS)
  2. Agence Nationale de la Recherche (ANR)

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A special pair model composed of two cofacial zinc porphyrins (acceptor) linked to a free base (donor) acts as an energy transfer dyad. Despite the absence of conjugation, pi pi*/charge transfer excited states and ultrafast energy transfer (similar to 5 ps) are noted.

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