Journal
CHEMICAL COMMUNICATIONS
Volume 46, Issue 36, Pages 6681-6683Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01708f
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- EPSRC
- STFC
- EastCHEM
- Leverhulme Trust
- EPSRC [EP/E06471X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/E06471X/1] Funding Source: researchfish
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Resistivity and powder X-ray diffraction measurements on Cs2Au2I6 up to 320 kbar pressure show that the suppression of Au+/Au3+ charge order above 55 kbar results in a non-metallic phase containing localised Au2+ states that is irreversibly amorphised above 120 kbar, and a gradual metallisation observed above 175 kbar may result from decomposition within the amorphous material.
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