4.7 Article

Formation of tetrameric water clusters driven by a cavitand template

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 1, Pages 88-90

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b917931c

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Funding

  1. EU [ICT 213219, ITN 215399]

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We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P=O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C-4 symmetry.

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