4.7 Article

An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 34, Pages 6311-6313

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cc01106a

Keywords

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Funding

  1. NSFC [90922031, 20821001]
  2. 973 Program [2007CB815302]
  3. Chinese Ministry of Education [109125]
  4. State Key Laboratory of Optoelectronic Materials and Technologies

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Solvothermal reaction of CoSO4 with 2,6-di-p-carboxyphenyl-4,4'-bipyridine affords a novel, octacobalt cluster based, (3,12)-connected porous framework, which exhibits gas sorption and spin-glassy magnetic behaviour.

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