4.7 Article

Enhanced photolabelling of luminescent Eu-III centres with a chelating antenna in a micellar nanodomain

Journal

CHEMICAL COMMUNICATIONS
Volume 46, Issue 14, Pages 2486-2488

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b919899g

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Funding

  1. European Research Council [FP7/2008-2013]
  2. ERC [208702]
  3. Region Aquitaine
  4. CNRS
  5. Ministere de la Recherche et de l'Enseignement Superieur
  6. TCD Postgraduate Scholarship

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Photoliberation of a caged, chelating naphthalene antenna greatly enhances the luminescence of a Eu-III-cyclen complex due to metal-bound water displacement and sensitization by the antenna, giving a lanthanide-labelling strategy in different media, being optimal in the presence of a TMADS surfactant.

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